Pyrolysis of Waste Castor Seed Cake: A Thermo-Kinetics Study

Abdullahi Muhammad Sokoto 1 * , Thallada Bhaskar 2

European Journal of Sustainable Development Research, Volume 2, Issue 2, Article No: 18.

https://doi.org/10.20897/ejosdr/81642

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Abstract

Biomass pyrolysis is a thermo-chemical conversion process that is of both industrial and ecological importance. The efficient chemical transformation of waste biomass to numerous products via pyrolysis reactions depends on process kinetic rates; hence the need for kinetic models to best design and operate the pyrolysis. Also, for an efficient design of an environmentally sustainable pyrolysis process of a specific lignocellulosic waste, a proper understanding of its thermo-kinetic behavior is imperative. Thus, pyrolysis kinetics of castor seed de-oiled cake (Ricinus communis) using thermogravimetric technique was studied. The decomposition of the cake was carried out in a nitrogen atmosphere with a flow rate of 100mL min-1 from ambient temperature to 900 °C. The results of the thermal profile showed moisture removal and devolatilization stages, and maximum decomposition of the cake occurred at a temperature of 200-400 °C. The kinetic parameters such as apparent activation energy, pre-exponential factor, and order of reaction were determined using Friedman (FD), Kissinger-Akahira-Sunose (KAS), and Flynn-Wall-Ozawa (FWO) kinetic models. The average apparent activation energy values of 124.61, 126.95 and 129.80 kJmol-1 were calculated from the slopes of the respective models. The apparent activation energy values obtained depends on conversion, which is an evidence of multi-step kinetic process during the pyrolytic decomposition of the cake. The kinetic data would be of immense benefit to model, design and develop a suitable thermo-chemical system for the conversion of waste de-oil cake to energy carrier.

Keywords

pyrolysis, heating rates, devolatilization, kinetic models, thermogravimetry

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Citation

Sokoto AM, Bhaskar T. Pyrolysis of Waste Castor Seed Cake: A Thermo-Kinetics Study. European Journal of Sustainable Development Research. 2018;2(2):18. https://doi.org/10.20897/ejosdr/81642

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