In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin

Kenechi Nwosu-Obieogu; Uduma Chinweikpe Kalu

doi:10.29333/ejosdr/7830

In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin

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Kenechi Nwosu-Obieogu ¹ ^* , Uduma Chinweikpe Kalu ¹

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¹ Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, NIGERIA
^* Corresponding Author

Abstract

This study is aimed at the modification of sesame seed oil to develop a biobased resin. Neat sesame seed oil was epoxidized via in-situ conventional method with peroxyacetic acid at 75^oC. Biobased resins were synthesized by further modifying the epoxidised oil with acrylic and methacrylic acid respectively at 90^oC in the presence of hydroquinone. Conversion rate of 76.54% and high oxirane content of 3.83% at a reaction time of 7 hours was achieved for the epoxidation process. FT-IR spectra of the acrylated and methacrylated epoxy resins of sesame seed oil were identified at 2710 and 3002cm^-1 respectively. This ascertained the functionalization of the acids used for modification and clearly demonstrates the potential of sesame seed oil for biobased resin synthesis.

Keywords

epoxidation
acrylation
methacrylation
sesame seed oil

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Article Type: Research Article

https://doi.org/10.29333/ejosdr/7830

EUR J SUSTAIN DEV RE, 2020 - Volume 4 Issue 3, Article No: em0121

Publication date: 17 Mar 2020

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Article Downloads: 81

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How to cite this article

Vancouver

Nwosu-Obieogu K, Kalu UC. In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin. EUR J SUSTAIN DEV RE. 2020;4(3):em0121. https://doi.org/10.29333/ejosdr/7830

APA

Nwosu-Obieogu, K., & Kalu, U. C. (2020). In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin. European Journal of Sustainable Development Research, 4(3), em0121. https://doi.org/10.29333/ejosdr/7830

AMA

Nwosu-Obieogu K, Kalu UC. In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin. EUR J SUSTAIN DEV RE. 2020;4(3), em0121. https://doi.org/10.29333/ejosdr/7830

Chicago

Nwosu-Obieogu, Kenechi, and Uduma Chinweikpe Kalu. "In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin". European Journal of Sustainable Development Research 2020 4 no. 3 (2020): em0121. https://doi.org/10.29333/ejosdr/7830

Harvard

Nwosu-Obieogu, K., and Kalu, U. C. (2020). In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin. European Journal of Sustainable Development Research, 4(3), em0121. https://doi.org/10.29333/ejosdr/7830

MLA

Nwosu-Obieogu, Kenechi et al. "In Situ Epoxidation of Sesame Seed Oil for Synthesis of a Bio-based Resin". European Journal of Sustainable Development Research, vol. 4, no. 3, 2020, em0121. https://doi.org/10.29333/ejosdr/7830